SiC单晶片切割力建模与自适应控制

Si C单晶因优良的物理和机械性能而大量用于大功率器件和IC行业。但由于材料的高硬度和高脆性,使其加工过程变得很困难。为此,分析了Si C单晶片切割过程,建立切割过程模型,通过F检验法进行系统阶次辨识,采用遗忘因子递推最小二乘算法在线估计模型参数,建立进给量与切割力的差分方程,设计基于最小方差自校正的切割力控制器,并进行实验验证。结果表明:控制器能够很好的跟踪不同信号,具有良好的鲁棒性,提高了Si C单晶片的加工效率和表面质量。     

双对苯醌的抗氧化活性分析及其固体发酵条件优化

为探索生物活性未知的双对苯醌（2,7-dihydroxy-3,6,9-trimethyl-9H-xanthene-1,4,5,8-tetraone，DTXT）的抗氧化活性，并提高其发酵产量，考察DTXT的还原力以及对超氧阴离子自由基、羟自由基、1,1-二苯基-2-三硝基苯肼（1,1-diphenyl-2-picrylhydrazyl，DPPH）自由基的清除效果，在单因素试验基础上，采用响应面法优化了DTXT产生菌瓶生顶孢霉（Acremonium cavaraeanum）CA022菌株的固体发酵培养基。结果表明：在200 μg/mL质量浓度下，DTXT的还原力与芦丁差异不显著，高于VE和2,6-二叔丁基-4甲基苯酚，对超氧阴离子自由基清除率达到67.00%，对羟自由基清除率达到78.83%，对DPPH自由基清除率达到76.53%。通过响应面试验，得到最佳培养基配方为葡萄糖0.773%、硝酸钠0.185%、H3BO3 0.032%、VB1 100 μg/100 g，在此条件下实际获得的DTXT产量为4 150.8 mg/kg，是优化前产量的（2 864.83 mg/kg）1.45 倍。     

镍钴电池Co-S负极材料的电化学特性研究

通过水热法制备Co-S材料,结合XRD分析其相结构,SEM和EDS分析其表面形貌及元素种类,采用充放电测试、循环伏安和交流阻抗法对其进行电化学特性研究。结果表明,该合金仅含有Co3S4、Co9S8和Co(OH)2, 结晶性良好,呈交叉生长的纳米薄片状,放电电流密度为150 mA/g时的最大放电容量为393.1mAh/g,50次循环后的容量保持率高达80.6%。当放电电流密度为1200 mA/g时,该电极的高倍率放电性能为79.3%。通过循环伏安和交流阻抗分析可知Co-S电极主要发生Co/Co(OH)2的法拉第反应,不可逆产物CoOOH的生成降低了活性物质的利用率,导致放电容量衰减。     

Estimates of pollutant temporal and spatial variability in commercial buildings from the joint urban 2003 field experiments

In this paper, we report on the indoor concentrations from a suite of full-scale outdoor tracer-gas point releases conducted in the downtown area of Oklahoma City in 2003. A point release experiment consisted of releases of sulfur hexafluoride (SF₆) in multiple buildings and from different outdoor locations. From the measurements, we are able to estimate the concentration variations indoors for a building operating under “typical” operating conditions. The mean indoor spatial coefficients of variation are 30% to 45% from a daytime outdoor release are around 80% during an outdoor evening release. Having estimates of the spatial coefficient of variation provides stakeholders, including first responders, with the likely range of concentrations in the building when little is known about the building characteristics and operating behavior, such as developing urban-scale hazard and consequence analyses. We show differences in indoor measurements at different distances to the release points, floors of the building, and heating, ventilation, and air conditioning system (HVAC) operation. We also show estimates at different time resolutions. The statistics show that in the studied medium to large commercial buildings, spatial differences would result in peak indoor concentrations in certain parts of the buildings that may be substantially higher than the building average. To our knowledge, very few tracer gas measurements have been conducted in buildings of this scope, particularly with measurements on multiple floors and within a floor. The resulting estimates of spatial variability provide a unique opportunity for hazard assessment, and comparison to multi-zone models.     

Quantification of grain boundary defect chemistry in a mixed proton-electron conducting oxide composite

Dual phase oxide membranes have shown promising hydrogen permeation fluxes in syngas applications due to their high mixed proton electron conduction (MPEC). However, the conductivity of grain boundaries can be many orders of magnitude lower than that of the bulk and so limits the total conductivity and hydrogen permeation. In this study, the three-dimensional nanoscale oxygen and cation distributions around grain and phase boundaries in a BaCe_0.8Y_0.2O_3-δ-Ce_0.8Y_0.2O_2-δ (BCY-YDC) membrane were quantified by atom probe tomography (APT) and related to average grain boundary conductivity measured by electrochemical impedance spectroscopy (EIS). Segregation varied among the general high-angle grain boundaries analyzed, but no trend from orientation analysis was determined. Correlative APT and electron energy loss spectroscopy (EELS) of one YDC grain boundary revealed composition and cerium valence information, respectively, allowing for the determination of vacancies at the grain boundary. While a specific MPEC membrane is characterized, the results are relevant to proton and electron conduction in a number of technologically important ceramics.     

Influence of Reaction Conditions on the Settling Behavior of Liquid-Liquid Dispersions

The settling behavior of liquid-liquid dispersions at ambient temperature and pressure is well investigated. However, little is known about the settling behavior of those systems at high pressure and high temperature. In this work, a novel stainless steel settling cell is presented, enabling investigations on liquid-liquid settling behavior at high pressures up to 130 bar. The settling behavior of a promising CO₂ hydrogenation reaction system is investigated by sequentially determining influences of dissolved CO₂, side components, and temperature.     

太西煤基新型功能炭材料的制备及其电化学性能

以宁夏太西煤高温直流电煅炉制备的煤基石墨为原料,利用Hummers氧化法制备了氧化石墨,然后分别采用水热法和高温膨胀法制备了煤基三维石墨烯气凝胶(3D-GA)和煤基膨胀石墨(EG)两种新型功能炭材料,并通过FTIR,XRD和SEM对其进行了表征,利用电化学工作站对其电化学性能进行了测试和比较。结果表明:在电流密度500 mA/g下,3D-GA和EG的比电容分别为206 F/g和214 F/g,相比煤基石墨烯粉体(G)的比电容113 F/g,分别提高了82.3%和89.4%;充放电循环1000圈后,3D-GA和EG的比电容保持率分别为95.1%和101%,3D-GA和EG均表现出良好的循环稳定性。     

波前传感器电铸镍层应力实时检测精度评估

目的 搭建电铸应力实时检测平台，评估其测量精度，并探明电化学沉积过程中镍层平均内应力的变化规律。方法 采用横向剪切波前传感器搭建电铸应力实时检测平台，通过测量在铸层应力作用下电铸基底弯曲的曲率半径，利用Stoney公式计算铸层平均应力。采用参考球面反射镜评估横向剪切波前传感器曲率半径的测量精度，并在0.5 A/dm2电流密度下进行电铸应力实时检测实验，对铸层平均应力测量极限进行评估，同时对检测误差进行分析。结果 横向波前传感器曲率半径测量精度为99.22%，在0.5 A/dm2电流密度下，所搭建的铸层应力实时检测平台可测量的最小厚度为5.1 μm，由曲率测量波动带来的应力检测误差为1.3 MPa。实验测得铸层平均应力随铸层厚度的增加而变大，当铸层厚度达到30 μm左右，铸层平均应力趋于稳定，应力大小为79.7 MPa。同时发现，当铸层厚度小于30 μm时，沿电铸基底长度方向的铸层平均应力明显大于宽度方向铸层平均应力，随铸层厚度的增加，两个方向的应力大小趋于等值。结论 采用横向剪切波前传感器搭建的电铸应力检测平台，能有效对铸层应力进行高精度的实时测量，为精密电铸过程中应力变化规律的研究提供了检测技术基础。